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Novel encapsulated ITO/arc-ZnO:TiO2 antireflective passivating layer for TCO conducting substrate prepared by simultaneous radio frequency-magnetron sputtering

Identifieur interne : 000825 ( Main/Repository ); précédent : 000824; suivant : 000826

Novel encapsulated ITO/arc-ZnO:TiO2 antireflective passivating layer for TCO conducting substrate prepared by simultaneous radio frequency-magnetron sputtering

Auteurs : RBID : Pascal:13-0220385

Descripteurs français

English descriptors

Abstract

A thermally stable multilayered transparent conducting oxide utilizing nanocomposite ZnO:TiO2 antireflection thin film (arc-ZnO:TiO2) on an indium-tin oxide (ITO) substrate has been prepared by radio frequency-magnetron sputtering. The effects of post-deposition annealing on the morphological, structural, optical and electrical properties were investigated with the aim to find the best conditions for the antireflection substrate. The X-ray diffraction behaviors of mixed type crystalline structures preferred at [222] and [101] between ITO and ZnO were observed, respectively. The grain size increased from 37.9 nm to 46.9 nm due to the aggregation of smaller grain during the annealing process. Average transmittances of approximately 82% were observed for all the samples in the range between 440 nm and 760 nm. A corresponding reduction in the reflectance of about 11% and 3% compared to bare ITO was achieved. The refractive index increased from 1.82 up to 2.0 due to the change in the packing density. For all ranges of annealing conditions, the arc-ZnO:TiO2 layers conserved the low resistivity of ITO at 1.96 × 10-4 Ω In other words, the oxygen consumed in the annealing process improved the crystallinity of the film without much change to the resistivity of the ITO-based substrate. The increment of the root mean square roughness from 2.12 nm to 3.21 nm evidenced by the atomic force microscopy analysis was supported by the increment of grain growth. .

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Pascal:13-0220385

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antireflective passivating layer for TCO conducting substrate prepared by simultaneous radio frequency-magnetron sputtering</title>
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<term>Antireflection thin film</term>
<term>Cathode sputtering</term>
<term>Conducting materials</term>
<term>Crystal structure</term>
<term>Doped materials</term>
<term>Electrical characteristic</term>
<term>Electrical properties</term>
<term>Grain size</term>
<term>Grain size analysis</term>
<term>ITO layers</term>
<term>Indium oxide</term>
<term>Multilayers</term>
<term>Nanocomposites</term>
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<term>Optical characteristic</term>
<term>Optical properties</term>
<term>Oxygen</term>
<term>Passivation</term>
<term>Radiofrequency</term>
<term>Reflectivity</term>
<term>Refractive index</term>
<term>Tin additions</term>
<term>Titanium oxide</term>
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<term>Couche mince antiréfléchissante</term>
<term>Couche ITO</term>
<term>Recuit</term>
<term>Caractéristique optique</term>
<term>Propriété optique</term>
<term>Propriété électrique</term>
<term>Caractéristique électrique</term>
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<term>Oxyde d'indium</term>
<term>Oxyde de zinc</term>
<term>Oxyde de titane</term>
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<term>Matériau transparent</term>
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<div type="abstract" xml:lang="en">A thermally stable multilayered transparent conducting oxide utilizing nanocomposite ZnO:TiO
<sub>2</sub>
antireflection thin film (arc-ZnO:TiO
<sub>2</sub>
) on an indium-tin oxide (ITO) substrate has been prepared by radio frequency-magnetron sputtering. The effects of post-deposition annealing on the morphological, structural, optical and electrical properties were investigated with the aim to find the best conditions for the antireflection substrate. The X-ray diffraction behaviors of mixed type crystalline structures preferred at [222] and [101] between ITO and ZnO were observed, respectively. The grain size increased from 37.9 nm to 46.9 nm due to the aggregation of smaller grain during the annealing process. Average transmittances of approximately 82% were observed for all the samples in the range between 440 nm and 760 nm. A corresponding reduction in the reflectance of about 11% and 3% compared to bare ITO was achieved. The refractive index increased from 1.82 up to 2.0 due to the change in the packing density. For all ranges of annealing conditions, the arc-ZnO:TiO
<sub>2</sub>
layers conserved the low resistivity of ITO at 1.96 × 10
<sup>-4</sup>
Ω In other words, the oxygen consumed in the annealing process improved the crystallinity of the film without much change to the resistivity of the ITO-based substrate. The increment of the root mean square roughness from 2.12 nm to 3.21 nm evidenced by the atomic force microscopy analysis was supported by the increment of grain growth. .</div>
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<sub>2</sub>
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<sub>2</sub>
layers conserved the low resistivity of ITO at 1.96 × 10
<sup>-4</sup>
Ω In other words, the oxygen consumed in the annealing process improved the crystallinity of the film without much change to the resistivity of the ITO-based substrate. The increment of the root mean square roughness from 2.12 nm to 3.21 nm evidenced by the atomic force microscopy analysis was supported by the increment of grain growth. .</s0>
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<s5>03</s5>
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<s5>03</s5>
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<s5>03</s5>
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<s0>Pulvérisation cathodique</s0>
<s5>04</s5>
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<s5>05</s5>
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<s5>05</s5>
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<s5>06</s5>
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<s5>06</s5>
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<s5>12</s5>
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<s0>Elektrische Groesse</s0>
<s5>12</s5>
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<s5>12</s5>
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<fC03 i1="13" i2="3" l="FRE">
<s0>Diffraction RX</s0>
<s5>13</s5>
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<s5>13</s5>
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<s5>14</s5>
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<s0>Grosseur grain</s0>
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<s5>18</s5>
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<s5>20</s5>
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<s0>Reflectivity</s0>
<s5>20</s5>
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<fC03 i1="21" i2="3" l="FRE">
<s0>Indice réfraction</s0>
<s5>21</s5>
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<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG">
<s0>Zinc oxide</s0>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="GER">
<s0>Zinkoxid</s0>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA">
<s0>Zinc óxido</s0>
<s5>23</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE">
<s0>Oxyde de titane</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG">
<s0>Titanium oxide</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="GER">
<s0>Titanoxid</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA">
<s0>Titanio óxido</s0>
<s5>24</s5>
</fC03>
<fC03 i1="25" i2="3" l="FRE">
<s0>Multicouche</s0>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="3" l="ENG">
<s0>Multilayers</s0>
<s5>25</s5>
</fC03>
<fC03 i1="26" i2="3" l="FRE">
<s0>Matériau conducteur</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="3" l="ENG">
<s0>Conducting materials</s0>
<s5>26</s5>
</fC03>
<fC03 i1="27" i2="X" l="FRE">
<s0>Matériau transparent</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="ENG">
<s0>Transparent material</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="SPA">
<s0>Material transparente</s0>
<s5>27</s5>
</fC03>
<fC03 i1="28" i2="3" l="FRE">
<s0>Nanocomposite</s0>
<s5>28</s5>
</fC03>
<fC03 i1="28" i2="3" l="ENG">
<s0>Nanocomposites</s0>
<s5>28</s5>
</fC03>
<fC03 i1="29" i2="3" l="FRE">
<s0>Oxygène</s0>
<s2>NC</s2>
<s5>29</s5>
</fC03>
<fC03 i1="29" i2="3" l="ENG">
<s0>Oxygen</s0>
<s2>NC</s2>
<s5>29</s5>
</fC03>
<fC03 i1="30" i2="3" l="FRE">
<s0>Matériau dopé</s0>
<s5>46</s5>
</fC03>
<fC03 i1="30" i2="3" l="ENG">
<s0>Doped materials</s0>
<s5>46</s5>
</fC03>
<fC03 i1="31" i2="3" l="FRE">
<s0>8107B</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="32" i2="3" l="FRE">
<s0>4279W</s0>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="33" i2="3" l="FRE">
<s0>7867</s0>
<s4>INC</s4>
<s5>58</s5>
</fC03>
<fC03 i1="34" i2="3" l="FRE">
<s0>6146</s0>
<s4>INC</s4>
<s5>59</s5>
</fC03>
<fC03 i1="35" i2="3" l="FRE">
<s0>ITO</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fC03 i1="36" i2="3" l="FRE">
<s0>ZnO</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fC03 i1="37" i2="3" l="FRE">
<s0>TiO2</s0>
<s4>INC</s4>
<s5>84</s5>
</fC03>
<fC03 i1="38" i2="3" l="FRE">
<s0>7363</s0>
<s4>INC</s4>
<s5>85</s5>
</fC03>
<fC03 i1="39" i2="3" l="FRE">
<s0>6837P</s0>
<s4>INC</s4>
<s5>86</s5>
</fC03>
<fN21>
<s1>203</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>International Conference on Surfaces, Coatings and Nanostructured Materials (NANOSMAT)</s1>
<s2>7</s2>
<s3>Prague CZE</s3>
<s4>2012-09-18</s4>
</fA30>
</pR>
</standard>
</inist>
</record>

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